Each Bittorrent client should prioritize the rarest pieces first by default, however these days there are a lot of clients downloading sequentially. The option you want is basically Super Seeding which is already available in Tixati. According to Help & Support
Super Seeding
This setting is useful for initial seeding of a new swarm. This will force peers to download pieces in a well-distributed pattern, which reduces the amount of outgoing pieces that need to be sent before peers complete downloading and become additional seeds.
I don't know exactly how it behaves after initial seeding of a torrent, but at worst it offers random pieces instead of all pieces to peers. It would be great if the Super Seeding feature would offer rarest pieces first, so that it would be useful after an initial seeding. Maybe it does already, I'm not sure.
If I may, I would request to add a separate status for Super Seeding torrents. Right now Tixati displays them as usual seeds with Seeding status. It's hard to find which transfers are at Super Seeding mode.